李雪超博士在Natl. Sci. Rev.上发表重要成果

时间:2021-05-24关键词:迟力峰教授课题组浏览量:817

Selective C(sp3) −H activation is of fundamental importance in processing alkane feedstocks to produce high-value-added chemical products. By virtue of an on-surface synthesis strategy, we report selective cascade dehydrogenation of n-alkane molecules under surface constraints, which yields monodispersed all-trans conjugated polyenes with unprecedented length controllability. We are also able to demonstrate the generality of this concept for alkyl-substituted molecules with programmable lengths and diverse functionalities, and more importantly its promising potential in molecular wiring.


文章链接:https://doi.org/10.1093/nsr/nwab093